Thorium copper phosphides: more diverse metal–phosphorus and phosphorus–phosphorus interactions than U analogues
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منابع مشابه
Thorium copper phosphides: more diverse metal-phosphorus and phosphorus-phosphorus interactions than U analogues.
To explore the chemical analogy between thorium and heavier actinides in soft anionic environments, three new thorium phosphides (ThCuP2, β-ThCu2P2, and ThCu5P3) have been prepared through solid-state reactions using CuI as a reaction promoter. The structure of ThCuP2 can be described as a filled UTe2-type with both dimeric P24- and monomeric P3- anions, in which Th is coordinated by eight P at...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2017
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c7dt02145c